Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 11, Issue 3, Pages 351-355Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201500531
Keywords
Buchwald-Hartwig reaction; catalysis; C-Cl bond activation; gold; nanoparticles; palladium
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Funding
- State Key Project of Fundamental Research for Nanoscience and Nanotechnology [2011CB932401, 2011CBA00500, 2012CB224802]
- National Natural Science Foundation of China [21221062, 21131004, 21390393, 21322107, 21471089, U1463202]
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It is highly challenging but desirable to develop efficient heterogeneous catalysts for C-Cl bond activation in coupling reactions. Here, we succeeded in synthesizing bimetallic Pd-Au nanoparticles through a convenient one-pot wet chemical route. The composition and alloyed structure of the as-prepared nanoparticles were fully characterized. We have evaluated the catalytic activity of these Pd-Au alloy catalysts in Buchwald-Hartwig reactions of aryl chlorides. The excellent catalytic activity of the as-obtained Pd-Au nanoparticles indicates that exploiting the catalytic power of nano-alloy catalysts could enable effective C-Cl bond activation suitable for cross-coupling reactions.
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