Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 33, Pages 11677-11680Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201501590
Keywords
amination; carbocations; electron transfer; homogeneous catalysis; photochemistry
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Funding
- Ministry of Education, Culture, Sports, Science of the Japanese Government [26288045, 15K13689]
- Grants-in-Aid for Scientific Research [26288045, 15K13689] Funding Source: KAKEN
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A simple and regiospecific aminohydroxylation of olefins by photoredox catalysis has been developed. N-protected 1-aminopyridinium salts are the key compounds and serve as amidyl radical precursors by the action of Ir photocatalysts, fac-[Ir(ppy)(3)] and [Ir(ppy)(2)(dtbbpy)](PF6) (ppy=2-pyridylphenyl, dtbbpy=4,4-di-tert-butyl-2,2-bipyridine). The present photocatalytic system allows for synthesis of vicinal aminoalcohol derivatives from olefins with various functional groups under mild reaction conditions with easy handling.
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