Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 15, Pages 5668-5678Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405855
Keywords
asymmetric catalysis; conjugate addition; metallation reactions; Michael addition; synthetic methods
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Funding
- EPSRC [EP/H003711/1]
- EPSRC [EP/H003711/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H003711/1] Funding Source: researchfish
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This Minireview discusses catalytic asymmetric conjugate addition and allylic alkylation reactions where the nucleophiles were generated in situ by hydrometallation or carbometallation. This exciting recent trend in asymmetric catalysis promises to expand the range of transformations available for the rapid and selective assembly of complex, functional molecules for both academic and industrial research. This Minireview aims to serve as a reference for studies reported to date and discusses the current state-of-theart, scope and limitations of these processes.
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