Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 48, Pages 17459-17465Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201503040
Keywords
aggregation-induced enhanced emission; BODIPY; J-aggregation; solid-state emission; vapor sensing
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Funding
- National Research Foundation of Korea (NRF) - Korean government (MSIP) [NRF-2015R1A2A2A01004632, NRF-2015R1A5A1008958]
- National Research Foundation of Korea [2015R1A5A1008958, 2015R1A2A2A01004632] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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4,4-Difluoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY) derivatives bearing varied substituents at the meso position (i.e., CF3, CH3, COOR, CHO, CN, Cl, iPr) were synthesized to elucidate the structure-property relationships that give rise to emissive J-aggregates. Several new BODIPY derivatives can be added to the previously reported 1,3,5,7-tetramethyl-8-trifluoromethyl derivative to the list of those forming J-aggregates, in addition to other dyes that are emissive in the solid state without forming J-aggregates.
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