Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 26, Pages 9364-9368Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201500639
Keywords
allylation; catalysts; CH bond activation; nickel; synthetic methods
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Funding
- Indian Institute of Technology Kanpur [IITK/CHM/20130187]
- IITK
- CSIR
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A one-step synthetic method was developed for allylation of benzamides using Ni(COD)(2)/RCO2H and [Ni(-H2O)(OOCCMe3)(2)(HOOCCMe3)(2)](2) (A) catalytic system. Efficient, well-defined, air and moisture-stable Ni-pivalate complex was isolated and employed in catalytic allylation. The influence of solvent on product selectivity was also investigated.
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