Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 13, Pages 4962-4965Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201500227
Keywords
C-P bond formation; dual catalysis; nickel; photochemistry; radicals
Categories
Funding
- National Science Foundation of China [21232003, 21202053, 21272087, 21472057]
- National Basic Research Program of China [2011CB808603]
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A novel and efficient C-P bond formation reaction of diarylphosphine oxides with aryl iodides was achieved by combining nickel catalysis and visible-light-induced photoredox catalysis. This dual-catalytic reaction showed a broad substrate scope, excellent functional group tolerance, and afforded the corresponding products in good to excellent yields. Compared with the previously reported use of photoredox/nickel dual catalysis in the construction of C-C bonds, the methodology described herein was observed to be the first to allow for C-heteroatom bond formation.
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