Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 38, Pages 13196-13200Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502193
Keywords
aggregation-induced emission; 1; 1-binaphthol; circular dichroism; circularly polarized luminescence; configuration inversion
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Funding
- National Natural Science Foundation of China [21174061, 51173078, 21172106, 21474048]
- open project of Beijing National Laboratory for Molecular Sciences
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Four aggregation-induced emission (AIE)-active chiral binaphthyl-based molecules, (R/S)-1 and (R/S)-2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis-conformation in pure THF solution to trans-conformation in THF/water mixtures.
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