Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 16, Pages 6144-6149Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405938
Keywords
aziridination; catalysis; crystal structure; olefins; silver cluster
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Funding
- NSERC-DG
- CFI
- ORF
- ERA
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An unprecedented trinuclear heteroleptic Ag-I complex was isolated using a stable multidentate 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligand. The obtained compound is an efficient catalyst for the direct aziridination of terminal olefins.
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