Journal
PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION
Volume 33, Issue 9, Pages 698-702Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ppsc.201600081
Keywords
gold; nanoparticles; nanorods; polymer conjugate
Funding
- European Research Council [ERC-2012-StG 306686]
- Elite Network Bavaria in the frame of the Elite Study Program Macromolecular Science
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A telechelic thermoresponsive polymer, -amino--thiol-poly(N-isopropylacrylamide) (H2N-PNiPAM-SH), is used as the polymeric glue to assemble gold nanoparticles (AuNPs) around gold nanorods (AuNRs) into a satellite structure. Prepared by reversible addition-fragmentation chain transfer polymerization followed by hydrazinolysis, H2N-PNiPAM-SH is able to interlink the two types of the gold building blocks with the thiol-end grafting on AuNRs and the amine-end coordinating on the AuNP surface. The density of the grafted AuNPs on AuNRs can be tuned by adjustingulted satellite-like assembly exhibits unique optical property that was resp the molar ratio between AuNPs and AuNRs in the feed. The resonsive to temperature change.
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