Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 42, Pages 14694-14698Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502338
Keywords
boronic acid; cross-coupling; fluorine; trifluoromethanesulfenamide; trifluoromethylthiolation
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Funding
- CNRS
- French Ministry of Research
- French Fluorine Network
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The most reactive 2nd generation of trifluoromethanesulfenamides undergoes a copper-catalyzed cross-coupling reaction with boronic acids to afford CF3S-molecules. Contrary to the previous methods in the literature, no base addition, no heating, and no large excess of reagents are required to obtain good results. Furthermore, a crucial role of a small amount of water to favor this reaction has been demonstrated. This constitutes the mildest described conditions for such a reaction.
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