Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 4, Pages 1349-1354Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201504507
Keywords
DFT calculations; germylene; pincer systems; stannylene; sulfonyl ligand
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Universite de Toulouse (UPS)
- Babes-Bolyai University of Cluj-Napoca
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The synthesis and characterization of an E2CE2 bis-sulfonyl aryl pincer ligand and its efficiency for the stabilization of compounds containing low-valent Group 14 elements (Ge and Sn) are reported. Complexation reaction of these metallylenes with iron or tungsten complexes resulted in the modulation of the oxygen atoms of the sulfonyl groups implicated in the stabilization of the Group 14 elements, demonstrating the original adjustable character of the bis-sulfonyl O2S-C-SO2 aryl pincer.
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