Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 22, Pages 8047-8051Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201500957
Keywords
electrophilic substitution; N-heterocycles; sodium chloride; synthetic methods; trifluoromethylthiolation
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Funding
- Fond der Chemischen Industrie
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A general and efficient methodology for the direct transition metal free trifluoromethylthiolation of a broad range of biologically relevant N-heteroarenes is reported employing abundant sodium chloride as the catalyst. This method is operationally simple, exhibits high functional group tolerance, and does not require protecting groups.
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