Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 19, Pages 7071-7076Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201406233
Keywords
amide functionalized frameworks; anion exchange; colorimetry; dynamic frameworks; separation
Categories
Funding
- CSIR
- DST [GAP/DST/CHE-12-0083]
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A novel porous metal-organic framework (MOF) architecture is formed by a neutral amide-functionalized ligand and copper(II). Upon desolvation, this compound undergoes a dynamic structural transformation from a one-dimensional (1D) porous phase to a two-dimensional (2D) non-porous phase that shows selective uptake of benzene over cyclohexane. The as-synthesized compound also acts as a visual colorimetric anion sensor for thiocyanate.
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