Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 19, Pages 7119-7126Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201500153
Keywords
carbon; doping; electrochemistry; MnO2; nanostructures; supercapacitors
Categories
Funding
- National Natural Science Foundation of China [NSFC 21271053, 21401032, 51472058, 21303131]
- Research Fund for the Doctoral Program of Higher Education of China [2011230411002]
- Natural Science Foundation of Heilongjiang Province [B201403]
- Harbin Sci.-Tech. Innovation Foundation [2014RFQXJ019]
- Fundamental Research Funds for the Central Universities of China
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A hierarchical hollow hybrid composite, namely, MnO2 nanosheets grown on nitrogen-doped hollow carbon shells (NHCSs@MnO2), was synthesized by a facile in situ growth process followed by calcination. The composite has a high surface area (251m(2)g(-1)) and mesopores (4.5nm in diameter), which can efficiently facilitate transport during electrochemical cycling. Owing to the synergistic effect of NHCSs and MnO2, the composite shows a high specific capacitance of 306Fg(-1), good rate capability, and an excellent cycling stability of 95.2% after 5000 cycles at a high current density of 8Ag(-1). More importantly, an asymmetric supercapacitor (ASC) assembled by using NHCSs@MnO2 and activated carbon as the positive and negative electrodes exhibits high specific capacitance (105.5Fg(-1) at 0.5Ag(-1) and 78.5Fg(-1) at 10Ag(-1)) with excellent rate capability, achieves a maximum energy density of 43.9Whkg(-1) at a power density of 408Wkg(-1), and has high stability, whereby the ASC retains 81.4% of its initial capacitance at a current density of 5Ag(-1) after 4000 cycles. Therefore, the NHCSs@MnO2 electrode material is a promising candidate for future energy-storage systems.
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