Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 14, Pages 5341-5344Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201500422
Keywords
cluster compounds; CO2 insertion; copper; density functional calculations; hydrides
Categories
Funding
- Center for Sustainable Use of Renewable Feedstocks (CenSURF), a National Science Foundation Center for Chemical Innovation (NSF CCI)
- Direct For Mathematical & Physical Scien [1240194] Funding Source: National Science Foundation
- Division Of Chemistry [1240194] Funding Source: National Science Foundation
Ask authors/readers for more resources
The copper hydride clusters [Cu14H12(phen)(6)(PPh3)(4)][X](2) (X=Cl or OTf; OTf=trifluoromethanesulfonate, phen=1,10-phenanthroline) are obtained in good yields by the reaction of [(Ph3P)CuH](6) with phen, in the presence of a halide or pseudohalide source. The complex [Cu14H12(phen)(6)(PPh3)(4)][Cl](2) reacts with CO2 in CH2Cl2, in the presence of excess Ph3P, to form the formate complex [(Ph3P)(2)Cu(kappa(2)-O2CH)], along with [(phen)(Ph3P)CuCl].
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
