Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 18, Pages 6682-6685Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201406532
Keywords
coordination polymer particles; fluorescent properties; J-type aggregates; metalloporphyrins; shape-transformation reactions
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Funding
- Ministero dell'Istruzione, dell'Universita - e della Ricerca, MIUR
- National Natural Science Foundation of China (NSFC) [21403280]
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Herein, nanorod structures and four-leaf clover structures of fluorescent zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine (ZnTPyP)-containing coordination polymer particles (CPPs) were first synthesized by a bottom-up strategy assisted by surfactants and then employed as seed structures for further shape-transformation reactions. We have successfully designed the morphological transformation for different dimensions, achieving the controlled formation of octahedron structures at both the nanometer scale and micrometer scale from the seed structures. Our approach illustrates a new method to design and synthesize metalloporphyrin-containing CPPs in a systematic and controllable manner.
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