Metallogels Self-Assembled from Linear Rod-Like Platinum Complexes: Influence of the Linkage

Two linear rod-like platinum complexes, which only differed in the linkage, were prepared. They both self-assemble into metallogels in nonpolar solvents; however, a very big contrast was observed. Unexpectedly, a much weaker gel was acquired upon replacing the ester linkage by an amide group. The intermolecular hydrogen bonding offered by the amide motif leads to a different stacking fashion and mechanism. The results demonstrated herein contribute to the rational design of metallogels as well as other functional supramolecular materials.