Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 12, Pages 4585-4589Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201406615
Keywords
copper; hydrogen evolution; liquid-liquid interface; nanoparticles
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Funding
- TUBITAK (The Scientific and Technological Research Council of Turkey) [211T185]
- COST Action [MP1106]
- TUBA (Turkish Academy of Sciences)
- TUBITAK [2210-C]
- Selcuk University Scientific Research Projects (BAP)
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The electrochemical deposition of Cu nanoparticles with an average diameter of approximately 25-35nm has been reported at liquid-liquid interfaces by using the organic-phase electron-donor decamethylferrocene (DMFc). The electrodeposited Cu nanoparticles display excellent catalytic activity for the hydrogen evolution reaction (HER); this is the first reported catalytic effect of Cu nanoparticles at liquid-liquid interfaces.
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