Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 14, Pages 5278-5300Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405779
Keywords
amination; amines; nitrenoids; nitrogen; synthetic methods
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Funding
- Israel Science Foundation [140/12]
- Fund for Promotion of Research at the Technion
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Among the numerous approaches and reagents employed for electrophilic amination, nitrenoids have long stayed out of the limelight. Here, we systematically review the discovery, structural features and chemical reactivity of these promising reagents. We highlight advances in applying the chemistry of nitrenoids as well as outline current limitations and future directions.
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