Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 51, Pages 18543-18546Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201503808
Keywords
Lewis base; 4-(N,N-dimethylamino)pyridine; NMR spectroscopy; phosphorus compounds; polycyclic phosphanes; structure elucidation
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Funding
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft [SCHU 1170/11-1]
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The reaction of the functionalized cyclo-tetraphosphane [ClP(mu-PMes*)](2) (Mes* = 2,4,6-tri-tert-butylphenyl) with different Lewis bases led to the formation of an unprecedented tricyclic hexaphosphane, Mes*P(6)Mes*. The formation of this compound was investigated by spectroscopic and theoretical methods, revealing an unusual ring expansion reaction. The title compound was fully characterized by experimental and computational methods.
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