Journal
ORGANOMETALLICS
Volume 35, Issue 23, Pages 3895-3902Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.6b00465
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- ELKE, University of Crete [KA 4066]
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Supported gold nanoparticles catalyze the unprecedented insertion of a silylborane into the C-O bond of oxetanes and unactivated epoxides, forming gamma- or beta-silyloxy boronates in good to excellent yields. In the silaboration process the boron moiety is acting as a nucleophile and the silyl as an electrophile. No external additives or ligands are required, while the catalytic system is recyclable and reusable.
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