Journal
ORGANOMETALLICS
Volume 35, Issue 16, Pages 2694-2700Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.6b00431
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The reactivity of cationic arene ruthenium complexes bearing a photoswitchable o-tosylamide azobenzene ligand toward various phosphorus nucleophiles was investigated. The resulting phosphine-ruthenium complexes containing an azobenzene ligand were isolated as the Z isomer. Under appropriate reaction conditions, quantitative triphenylphosphine photorelease from the complex was achieved through Z -> E isomerization of the ligand. This process was applied to the photoinitiation of the catalytic aza-Morita-Baylis-Hillman reaction.
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