Journal
ORGANOMETALLICS
Volume 35, Issue 10, Pages 1347-1349Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.6b00054
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Funding
- National Basic Research Program of China [973-2015CB856600]
- National Nature Science Foundation of China [21225210, 21532009, 21421091, 21472219]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1464734] Funding Source: National Science Foundation
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In this work, a mechanistic study of silver-catalyzed oxidative aminofluorination of alkynyl-imine has been carried out. Kinetic data support a reaction pathway involving fast amination of alkyne to mesoionic carbene silver complexes (MIC)(n)Ag(I) (n = 1 or 2). The rate-determining step of the reaction is the fluorination of the Ag species supported by a single MIC.
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