Journal
ORGANIC LETTERS
Volume 18, Issue 3, Pages 356-359Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03185
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Funding
- CSIR [02(0201)/14/EMR-II]
- DST [SB/FT/CS-012/2014]
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A ruthenium catalyzed intramolecular C-S coupling reaction of N-arylthioureas for the synthesis of 2-aminobenzothiazoles has been developed. Kinetic, isotope labeling, and computational studies reveal the involvement of an electrophilic ruthenation pathway instead of a direct C-H activation. Stereo electronic effect of meta-substituents on the N-arylthiourea dictates the final regioselective outcome of the reaction.
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