Journal
ORGANIC LETTERS
Volume 18, Issue 18, Pages 4594-4597Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02243
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Funding
- National Natural Science Foundation of China [21102134, 21172200]
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A simple and facile protocol for palladium-catalyzed picolinamide-directed C8-H amination of 1-naphthylamine derivatives with simple secondary aliphatic amines was developed, thereby providing a new route to 1,8-naphthalenediamine derivatives. It is noteworthy that the picolinamide moiety as a bidentate directing group may play a key role in this regioselective transformation.
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