Journal
ORGANIC LETTERS
Volume 18, Issue 4, Pages 712-715Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03685
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Funding
- National Natural Science Foundation of China [21102071, 21472082]
- Fundamental Research Funds for the Central Universities [020514380018]
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An efficient cascade trifunctioalization reaction of alkynoates with N-iodosuccinimide has been developed which proceeds through iodination, aryl migration, decarboxylation, and second iodination. This reaction represents an example of 1,1-difunctionalization of the acetylene bond and also provides a new strategy for the preparation of 1,1-diiodoalkenes.
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