Journal
ORGANIC LETTERS
Volume 18, Issue 7, Pages 1646-1649Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00512
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Funding
- EPSRC
- AstraZeneca
- Engineering and Physical Sciences Research Council [1468092] Funding Source: researchfish
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An azidation method for C-N bond formation at benzylic C-H positions is described using copper-catalyzed visible light photochemistry and the Zhdankin azidoiodinane reagent. The method is applicable to a wide range of substrates bearing different functional groups and having a primary, secondary, or tertiary benzylic position, and is thought to proceed through a radical chain reaction.
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