Journal
ORGANIC LETTERS
Volume 18, Issue 5, Pages 1000-1003Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00120
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Funding
- National Natural Science Foundation [21172240, 21421002, 21472222, 21502214]
- National Basic Research Program of China [2015CB931900, 2012CBA01200]
- Science and Technology Commission of Shanghai Municipality [14ZR1448800]
- Chinese Academy of Sciences [XDA02020105, XDA02020106]
- Syngenta Ph.D. Fellowship
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A new method has been developed for the Cu-catalyzed C-H trifluoromethylation of 3-arylprop-1-ynes for the selective construction of allenic Csp(2)-CF3 and propargyl Csp(3)-CF3 bonds. The selective formation of allenic Csp(2)-CF3 and propargyl Csp(3)-CF3 bonds can be controlled by modifying the reaction conditions.
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