Journal
ORGANIC LETTERS
Volume 18, Issue 19, Pages 5098-5101Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02541
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Funding
- National Research Foundation of Korea [2014R1A5A1011165]
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Aryl hydrazides with a ketone or aldehyde containing side chains linked to the meta-position of the aromatic ring undergo acid-promoted intramolecular Fischer indole synthesis to generate 3,4-fused tricyclic indoles. The preparative utility of this conceptually new synthetic approach, which does not require prefunctionalization of the indole ring, was demonstrated by its application to a concise total synthesis of (-)-aurantioclavine.
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