Journal
ORGANIC LETTERS
Volume 18, Issue 10, Pages 2339-2342Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00744
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Funding
- KAKENHI from JSPS [26810056]
- Hattori Hokokai Foundation
- World Premier International Research Center Initiative (WPI) program
- Grants-in-Aid for Scientific Research [26810056, 16K13962, 26288023] Funding Source: KAKEN
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A scandium-triflate-catalyzed arylative desulfonation of diarylmethyl phenyl sulfones with arenes and heteroarenes was established. A variety of both sulfone and arene substrates were reacted to afford symmetric and nonsymmetric triarylmethanes in good yields. Further transformations of the resulting triarylmethanes and application to the concise synthesis of a bactericidal agent analogue were also demonstrated.
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