Journal
ORGANIC LETTERS
Volume 18, Issue 6, Pages 1478-1481Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00442
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- ICSN
- CNRS
- Labex Charmmmat
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A general and practical photoredox-promoted addition of nucleophiles to N-acylimines generated in situ from alpha-amidosulfides using Ru(bpy)(3)(PF6)(2) as the photocatalyst is reported. The broad scope of the reaction toward various nucleophiles and amidosulfide derivatives was explored. This novel protocol provides a rapid, mild, and efficient access to valuable alpha,alpha-disubstituted amines in respectable yields.
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