Journal
ORGANIC LETTERS
Volume 18, Issue 21, Pages 5728-5731Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02994
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Funding
- National Research Foundation of Korea (NRF) - Ministry of Education and Ministry of Science, ICT and future Planning [2012M3A7B4049644, 2015R1A2A2A01002559, 2014-011165]
- National Research Foundation of Korea [2015R1A2A2A01002559] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A highly efficient and facile metal-free, one-pot reaction has been developed to afford diversely substituted N-arylbenzimidazoles through chemoselective in situ generation of N,N'-diarylamidines from arenediazonium salts, nitrites, and free anilines. The advantages of this protocol consist of the operationally easy and simple one-pot procedure under metal-free and mild conditions, the direct use of inexpensive and commercially available chemicals, and thus, a cost-effective and greener process.
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