Journal
ORGANIC LETTERS
Volume 18, Issue 23, Pages 6168-6171Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03179
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Funding
- National Natural Science Foundation of China [21372204]
- Program for Innovative Research Team of Zhejiang Sci-Tech University [13060052-Y]
- Zhejiang Sci-Tech University 521 project
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A facile rhodium-catalyzed transannulation of 1-sulfonyl-1,2,3-triazoles with beta-diketones was realized, and a series of multisubstituted 2-carbonylpyrroles were synthesized efficiently (up to 94% yield). The protocol features several advantages, such as readily available materials, mild reaction conditions, a concise operating procedure, a broad reaction scope, and excellent regioselectivity when benzoylacetone derivatives were used.
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