Journal
ORGANIC LETTERS
Volume 18, Issue 11, Pages 2700-2703Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01165
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Funding
- National Natural Science Foundation of China [NSFC 21404096, U1463202]
- Fundamental Research Funds for the Central Universities of China [WK2060190026, WK3430000001]
- Anhui Provincial Natural Science Foundation [1608085MB24]
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An aldehyde-selective aerobic Wacker-Tsuji oxidation is developed. Using tert-butyl nitrite as a simple organic redox cocatalyst instead of copper or silver salts, a variety of aldehydes were achieved as major products in up to 30/1 regioselectivity as well as good to high yields at room temperature.
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