Journal
ORGANIC LETTERS
Volume 18, Issue 9, Pages 2050-2053Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00665
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Funding
- National Natural Science Foundation of China [21472106, 21272132]
- National Key Basic Research Program of China (973 program) [2012CB933402]
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Cp2TiCl2-catalyzed regioselective hydrocarboxylation of alkenes with CO2 to give carboxylic acids in high yields has been developed in the presence of (PrMgCl)-Pr-i. The reaction proceeds with a wide range of alkenes under mild conditions. Styrene and its derivatives can transform to alpha-aryl carboxylic acids, and aliphatic alkenes can transform to form alkanoic acids.
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