Journal
ORGANIC LETTERS
Volume 18, Issue 9, Pages 2174-2176Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00793
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Funding
- Swiss National Science Foundation [SNF 152898]
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An enantiospecific approach to the synthesis of optically active, trisubstituted allenes from chiral propargylic benzoates and arylboronic acids has been developed. The transformation is catalyzed by a Rh-(P,olefin) complex formed in situ from [{Rh(cod)Cl}(2)] and a readily available phosphoramidite ligand. The method furnishes an assortment of diverse allenes in high yields and excellent enantiospecificity under mild conditions.
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