Journal
ORGANIC LETTERS
Volume 18, Issue 15, Pages 3514-3517Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01008
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Funding
- National Natural Science Foundation of China [21490572, 21420102003]
- Pearl River S&T Nova Program of Guangzhou [201610010160]
- Fundamental Research Funds for the Central Universities [2015ZY001]
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A new approach to construct 2,3-disubstituted quinolines is described via Pd-catalyzed oxidative cyclization of o-vinylanilines and alkynes with molecular oxygen. This transformation is supposed to undergo intermolecular amination of alkyne, insertion of the olefin, and oxidative cleavage of C-C bond sequence.
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