Journal
ORGANIC LETTERS
Volume 18, Issue 12, Pages 2840-2843Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01091
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Funding
- Xi'an Jiaotong University
- NSFC [21472145]
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A rare Ru-catalyzed highly selective synthesis of: 3,4-dihydroisoquiuolines or isoquinolines is accomplished via a redox-divergent hydrogen-retentive or, hydrogen-releasing fashion. Notably, high cis-selectivity of 3,4-dihydroisoquino lines is achieved. Potential applications, are shown by gram,: scale reactions and very concise synthesis of N-containing polycyclic aromatic compounds. Primary mechanistic investigations indicate that the sequence of the major pathway involves Ru-catalyzed C-H activation, alkyne insertion, and subsequent 6 pi-electrocyclization.
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