Journal
ORGANIC LETTERS
Volume 18, Issue 16, Pages 3956-3959Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01675
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Funding
- MEXT [26810058]
- JST
- Grants-in-Aid for Scientific Research [26810058] Funding Source: KAKEN
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A method for the arylboration of 1-arylalkenes with bis(pinacolato)diboron and aryl chlorides or tosylates by cooperative Ni/CU catalysis has been developed, which affords 2-bory1-1,1-diarylalkanes in high regio- and stereoselectivity. Under the applied conditions, this method is tolerant toward various functional groups, including silyl ether, alkoxycarbonyl, and aminocarbonyl moieties.
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