Journal
ORGANIC LETTERS
Volume 18, Issue 18, Pages 4634-4637Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02255
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Funding
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1061]
- Program for Innovative Research Team in Science and Technology in University of Henan Province [15IRTSTHN003]
- Education Department of Henan Province, China [2013GGJS-059]
- Henan Normal University [2011-8]
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An efficient, one-pot strategy with high selectivity and high atom economy for the synthesis of o-aminobenzamides has been developed via palladium-catalyzed ortho-selective C-H oxidative carbonylation of N-substituted anilines with CO and primary amines. A wide range of N-substituted anilines and primary amines can be tolerated in this transformation to afford the corresponding o-aminobenzamides in moderate to excellent yields under mild conditions.
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