Journal
ORGANIC LETTERS
Volume 18, Issue 23, Pages 6164-6167Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03172
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Funding
- Spanish MINECO [CTQ2013-40591-P, CTQ2016-75986-P, CTQ2014-51912-REDC]
- Gobierno del Principado de Asturias [GRUPIN14-006]
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An unprecedented hydration/transfer hydrogenation tandem process for the catalytic conversion of beta-ketonitriles into synthetically useful beta-hydroxyamides in water has been developed, making use of the ruthenium(II) complex [RuCl2(n(6)-p-cymene){P(4-C6H4F)(2)Cl}] in combination with sodium formate.
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