Journal
ORGANIC LETTERS
Volume 18, Issue 15, Pages 3570-3573Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01555
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Funding
- MINECO (Spain) [CTQ2013-46459-C2-01-P, CTQ2013-46459-C2-02-P, CTQ2014-51912-REDC]
- MINECO
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Gold mesoionic carbenes having, a chiral sulfoxide group attached to the C4 position of the five membered ring have been prepared and tested as catalysts in the cycloisomerization of enynes. These new catalysts are very efficient, with the sulfoxide moiety playing a key role in their activity and the N1-substituent in control of the regioselectivity of these processes.
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