Journal
ORGANIC LETTERS
Volume 18, Issue 4, Pages 732-735Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03705
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Funding
- NIGMS [R01 GM 113878]
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A visible-light, single-electron-transfer (SET), photoredox cross-coupling for the synthesis of alpha-alkoxyketones has been developed. In this method, various aliphatic and aromatic acyl chlorides were successfully coupled with structurally diverse potassium alkoxymethyltrifluoroborates, producing the corresponding alpha-alkoxyketones with high yields. In this operationally simple and mild cross-coupling protocol, the desired ketones are obtained in one step from bench stable starting materials by a bond connection that is unique to both alkylboron chemistry and photoredox/Ni catalysis.
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