Journal
ORGANIC LETTERS
Volume 18, Issue 13, Pages 3270-3273Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01516
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Funding
- National Natural Science Foundation of China [21472082]
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The discovery of detrifluoroacetylative in situ generation of a new type of fluorinated amide enolates derived from 3-fluoroindolin-2-one and their asymmetric Mannich additions with sulfinylaldimines bearing fluoroalkyl groups is reported, which afforded alpha-fluoro-beta-(fluoroalkyl)-beta-aminoindolin-2-ones containing C-F quaternary stereogenic centers with excellent yields and high diastereoselectivities.
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