Journal
ORGANIC LETTERS
Volume 18, Issue 9, Pages 2212-2215Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00844
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Funding
- Thousand Plan program
- Bayer Investigator Fellow
- Tsinghua-Peking Centre for Life Sciences (CLS)
- Tsinghua University
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The benzonitrile unit is widely found in natural products, pharmaceuticals, and agrochemicals. Synthesis of benzonitriles has received considerable interests from the chemical community over the last few decades. Present synthetic protocols mainly rely on the pre-existing benzene core to install a cyano moiety. A new NHC-catalyzed [4 + 2]-enzannulation protocol is reported to assemble the benzonitrile framework.
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