Journal
ORGANIC LETTERS
Volume 18, Issue 11, Pages 2754-2757Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01231
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Funding
- JSPS [26293001, 26410108]
- ACT-C, JST
- Grants-in-Aid for Scientific Research [16J03988, 26410108, 26293001] Funding Source: KAKEN
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By using a palladium catalyst with ZnEt2, activated viriylcyclopropanes were successfully converted into the corresponding beta,gamma-unsaturated carboxylic acid's in high yields under a CO2 atmosphere (1 atm). The intermediate in this reaction is thought to be a nucleophilic eta-allylethylpalladium species, which would be produced from pi-allylpalladium and ZnEt2 (umpolung reactivity).
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