4.8 Article

Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans

Journal

ORGANIC LETTERS
Volume 18, Issue 24, Pages 6284-6287

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03143

Keywords

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Funding

  1. MEXT [15H05756, 16K05694]
  2. JSPS
  3. Grants-in-Aid for Scientific Research [15H05756, 14J05174, 16K05694] Funding Source: KAKEN

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A rhodium(II)-catalyzed reaction of N-sulfonyl-1,2,3-triazoles with 2-(siloxy)furans is reported. Either open-chain penta-2,4-dien-1-imines or cyclic 1,2-dihydropyridines are selectively obtained depending on the ligand on rhodium(II).

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