Journal
ORGANIC LETTERS
Volume 18, Issue 21, Pages 5460-5463Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02527
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Funding
- National Natural Science Foundation of China [21202049]
- Recruitment Program of Global Experts (1000 Talents Plan)
- Natural Science Foundation of Fujian Province [2016J01064]
- Fujian Hundred Talents Plan and Program of Innovative Research Team of Huaqiao University [Z14X0047]
- Graduate Innovation Fund of Huaqiao University
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A palladium-catalyzed 1,2-arylboration of vinylarenes with aryldiazonium tetrafluoroborates and bis(pinacolato)-diboron has been disclosed. It is reported for the first time that styrene derivatives can be successfully employed as good substrates for 1,2-arylboration of alkenes. Mechanistic studies suggest that no Pd-H reinsertion occurred under our standard conditions, which is the key for the success of this transformation.
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