Journal
ORGANIC LETTERS
Volume 18, Issue 22, Pages 5840-5843Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02877
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Funding
- Pazy Foundation
- Elsa-Neumann-Stipendium
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Facile, one-pot conversion of free base 5,10,15-tris(pentafluorophenyl)corrole, (H-3)tpfc, into the coinage metal complexes of 2,3,17,18-tetraiodo-5,10,15-tris(pentafluorophenyl)corrole, (I-4-tpfc)M (M = Cu, Ag, Au), is reported. The iodination/metalation procedures provide much higher yields and larger selectivity than both conceivable stepwise syntheses. Photophysical analysis shows that the gold(III) complex (I-4-tpfc)Au displays phosphorescence at room temperature and a substantial quantum yield for singlet oxygen formation.
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