4.8 Article

Free-Radical Carbocyanation of Cyclopropenes: Stereocontrolled Access to All-Carbon Quaternary Stereocenters in Acyclic Systems

Journal

ORGANIC LETTERS
Volume 18, Issue 23, Pages 6156-6159

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03163

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Funding

  1. H2020 Marie-Curie IF Program (Leucophyl) [655527]
  2. University of Bordeaux
  3. CNRS
  4. Marie Curie Actions (MSCA) [655527] Funding Source: Marie Curie Actions (MSCA)

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Free-radical carbocyanation of cyclopropenes offers straightforward access to tetrasubstituted cyclopropanes in satisfying yields with moderate diastereoselectivity. The incorporation of various functional groups on the cyclopropane ring allows a subsequent base mediated ring-opening reaction leading to functionalized acyclic systems having an all-carbon quaternary stereocenter.

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